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Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates
kinetic and photochemical data atmospheric chemistry heterogeneous reactions solid substrates
2010/10/11
This article, the fifth in the ACP journal series, presents data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the heterogeneous processes on ...
Coupling aerosol surface and bulk chemistry with a kinetic double layer model (K2-SUB): oxidation of oleic acid by ozone
aerosol surface bulk chemistry a kinetic double layer model oleic acid ozone
2010/8/13
We present a kinetic double layer model coupling aerosol surface and bulk chemistry (K2-SUB) based on the PRA framework of gas-particle interactions (Pöschl-Rudich-Ammann, 2007). K2-SUB is applie...
Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone
Kinetic multi-layer model aerosol surface bulk chemistry interfacial transport and bulk diffusion oleic acid ozone
2010/8/12
In this study we explore and exemplify the effects of bulk diffusion on the rate of reactive gas uptake for a simple reference system, the ozonolysis of oleic acid particles, in comparison to experime...
Kinetic double-layer model of aerosol surface chemistry and gas-particle interactions (K2-SURF): Degradation of polycyclic aromatic hydrocarbons exposed to O3, NO2, H2O, OH and NO3
Kinetic double-layer model aerosol surface chemistry gas-particle interactions K2-SURF
2009/12/31
We present a kinetic double-layer surface model (K2-SURF) that describes the degradation of polycyclic aromatic hydrocarbons (PAHs) on aerosol particles exposed to ozone, nitrogen dioxide, water vapor...
Kinetic modeling of nucleation experiments involving SO2 and OH: new insights into the underlying nucleation mechanisms
Kinetic modeling nucleation experiments SO2 OH underlying nucleation mechanisms
2009/11/9
Nucleation is an important source of atmospheric aerosols which have significant climatic and health implications. Despite intensive theoretical and field studies over the past decades, the dominant n...
Kinetic nucleation and ions in boreal forest particle formation events
Kinetic nucleation ions boreal forest particle
2009/3/10
In order to gain a more comprehensive picture on different mechanisms behind atmospheric particle formation, measurement results from QUEST 2-campaign are analyzed with an aid of an aerosol dynamic mo...
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species
Evaluated kinetic atmospheric chemistry gas phase reactions
2009/3/5
This article, the first in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on GasKinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and ...
Kinetic study of the gas-phase reaction of atomic chlorine with a series of aldehydes
Kinetic study gas-phase reaction atomic chlorine aldehydes
2009/2/19
The reactions of Cl atoms with a series of unsaturated aldehydes have been investigated for the first time using a relative method. In order to obtain additional information for a qualitative structur...
On the isolation of elemental carbon (EC) for micro-molar 14C accelerator mass spectrometry: development of a hybrid reference material for 14C-EC accuracy assurance, and a critical evaluation of the thermal optical kinetic (TOK) EC isolation procedure
elemental carbon EC TOK
2009/2/18
The primary objective of the research reported here has been the development of a hybrid reference material (RM) to serve as a test of accuracy for elemental carbon (EC) isotopic (14C) speciation meas...
Kinetic model framework for aerosol and cloud surface chemistry and gas-particle interactions – Part 2: Exemplary practical applications and numerical simulations
Kinetic model framework cloud surface chemistry gas-particle interactions Exemplary practical applications numerical simulations
2008/12/26
A kinetic model framework with consistent and unambiguous terminology and universally applicable rate equations and parameters for aerosol and cloud surface chemistry and gas-particle interactions has...
Kinetic model framework for aerosol and cloud surface chemistry and gas-particle interactions – Part 1: General equations, parameters, and terminology
Kinetic model framework cloud surface chemistry gas-particle interactions
2008/12/26
Aerosols and clouds play central roles in atmospheric chemistry and physics, climate, air pollution, and public health. The mechanistic understanding and predictability of aerosol and cloud properties...
Kinetic modeling of secondary organic aerosol formation: effects of particle- and gas-phase reactions of semivolatile products
Kinetic modeling secondary organic aerosol formation semivolatile products
2008/12/16
The distinguishing mechanism of formation of secondary organic aerosol (SOA) is the partitioning of semivolatile hydrocarbon oxidation products between the gas and aerosol phases. While SOA formation ...
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III – gas phase reactions of inorganic halogens
kinetic photochemical data atmospheric chemistry inorganic halogens
2008/12/2
This article, the third in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and...