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SPECTROSCOPIC STUDIES OF NON-COVALENT METAL ION-LIGAND INTERACTIONS
SPECTROSCOPIC STUDIES ON-COVALENT METAL ION-LIGAND
2014/11/20
Non-covalent interactions between metal ions and ligands such as water and methane have been extensively studied due to their biological and industrial importance. Gas phase studies can reveal the fun...
双(1-甲基咪唑-2-基)甲酮、双(1-甲基咪唑-2-基)甲烷及双(1-甲基咪唑-2-基)乙烯与第六族羰基金属化合物的反应研究(Reactivity of (Mim)2C=O, (Mim)2CH2 and (Mim)2C=CH2 (Mim=1-Methylimidazole-2-yl) with Group 6 Metal Carbonyl Complexes)
1-甲基咪唑 晶体结构 第六族羰基金属化合物
2010/8/18
本文研究了羰基钼(钨)与双(1-甲基咪唑-2-基)甲酮和双(1-甲基咪唑-2-基)甲烷以及双(1-甲基咪唑-2-基)乙烯的反应,获得了6个双齿螯合的双(1-甲基咪唑-2-基)甲酮,双(1-甲基咪唑-2-基)甲烷和双(1-甲基咪唑-2-基)乙烯四羰基金属衍生物,以及1个单齿配位的双(1-甲基咪唑-2-基)乙烯五羰基钨化合物。它们的结构通过红外,核磁以及X-射线单晶衍射分析得到确证。所有这些新化合物的...
Microwave-Assisted Synthesis of Some Metal-Free Phthalocyanine Derivatives and a Comparison with Conventional Methods of their Synthesis
Synthesis metal-free phthalocyanines microwave irradiation conventional heating lithium pentanol
2010/4/9
Synthesis of metal-free 2,9(10),16(17),23(24)-tetra(3,5- dimethylphenoxy) phthalocyanine, 2,9(10),16(17), 23(24)-tetra(4- tert-butylphenoxy) phthalocyanine, and 2,9(10),16(17),23(24)-tetra(3,5- di-ter...
Synthesis and Characterization of a Novel Metal Phosphonate, Zirconium (IV)-Hydroxy Ethylidene Diphosphonate, and Its Application as an Ion Exchanger
Inorganic ion exchanger metal phosphonate tetravalent metal acid salt zirconium-hydroxy ethylidene diphosphonate Zr(IV) phosphonate
2010/4/16
A novel hybrid ion exchange material, Zirconium-hydroxy ethylidene diphosphonate [ZrHEDP], of the class of tetravalent metal acid (TMA) salts has been synthesized by the sol-gel technique. The materia...
专著信息
书名
“Aggregate Manganese Schiff Base Moieties by Terephthalate or Acetate: Dinuclear Manganese and Trinuclear Mixed Metal Mn2/Na Complexes,
语种
英文
撰写或编译
作者
C. Chen,D. Huang,X. Zhang,F. Chen,H. Zhu...
过渡金属氧化物渗透对LSM-YSZ阴极性能的影响(Transition Metal Oxide Infiltration Effect on the Performance of LSM-YSZ Cathode)
SOFC LSM-YSZ阴极 过渡金属氧化物 渗透法
2010/8/24
Transition metal (Mn, Fe, Co, Ni, Cu) oxide was formed in LSM-YSZ cathode by nitrate solution infiltration method. LSM-YSZ/YSZ/LSM-YSZ symmetric cell performance at intermediate temperature range 600~...
过渡金属掺杂Ru-Se簇合物电催化剂氧还原性能的对比研究(Comparison of Electrocatalytic O2 Reduction Performances between Transition Metal Doped Ru-Se Cluster)
氧电还原 Ru纳米簇硫族化合物 电催化剂 抗甲醇性
2010/8/24
采用羰基金属化合物低温合成法制备了不同掺杂元素的M-Ru-Se(M=Fe,W,Mo)簇合物,并应用旋转圆盘电极电位扫描法测试簇合物的电催化活性及其抗甲醇性,采用TEM、XRD、EDS技术表征催化剂的微观形貌、结构和组成。结果显示,掺杂过渡元素对簇合物的催化活性及其抗甲醇性有明显的影响,其中Mo-Ru-Se的还原电流最高,催化活性最高,W-Ru-Se次之,Fe-Ru-Se最低;电解质中加入甲醇后,W...
Examination of Gold as a Metal Promoter of Sulphated Zirconia in n-Heptane Isomerisation at Low Temperature
Examination of Gold in n-Heptane Isomerisation Low Temperature
2010/4/19
Isomerisation of nC7 over a sulphated zirconia (SZ)-based bifunctional catalyst was studied at 150 °C. Au, Ir, Pd and Pt were used as promoters of SZ. The first objective was the production of C7 isom...
Synthesis and Vibrational Spectroscopic Study of Some Metal(II) Halide and Tetracyanonickelate Complexes of Isonicotinic Acid
Infrared spectra isonicotinic acid metal halide complexes tetracyanonickelate complexes
2010/4/19
The M(IN)2Ni(CN)4 [where M: Cu, Mn, Zn, IN: Isonicotinic acid, abbreviated to M-Ni-IN] tetracyanonickelate and some metal halide complexes with the following stoichiometries: Cu(IN)X2 (X:Br,I), Cd(IN)...
Metal Complexes of Schiff Bases: Preparation, Characterization, and Biological Activity
2-thiophenecarboxaldehyde 2-furancarboxaldehyde 2-aminothiophenol o-phenylenediamine
2010/4/19
Metal Complexes of Schiff Bases: Preparation, Characterization, and Biological Activity.
Optimization of the Nonaqueous Capillary Electrophoresis Separation of Metal Ions Using Mixture Design and Response Surface Methods
Nonaqueous capillary electrophoresis metal ions mixture design response surface methods
2010/4/19
Mixture experimental design was used to enhance the separation selectivity of metal ions in nonaqueous capillary electrophoresis. The separation of cations (Ag, Fe, Cr, Mn, Cd, Co, Pb, Ni, Zn and Cu) ...
pH值和金属离子对尖吻蝮蛇抗凝血因子Ⅱ二级结构的影响(The Effects of pH and Metal Ions on the Secondary Structure of Anticogulation Factor Ⅱ Studed by CD Spectroscopy)
抗凝血因子Ⅱ 酸度(pH) 二级结构 圆二色谱
2010/8/25
圆二色谱(CD谱)测量表明,尖吻蝮蛇抗凝血因子Ⅱ(ACF Ⅱ)与抗凝血因子Ⅰ(ACF Ⅰ)的二级结构十分相似,它们的主要骨架构象都为反平行β-折叠和α-螺旋结构。pH值对天然ACF Ⅱ的构象有一定的影响,pH值从3到10增大时,α-螺旋含量逐渐减少,反平行β-折叠含量逐渐增大。钙和其他二价金属离子对ACF Ⅱ的骨架结构没有明显影响。三价稀土离子使ACF Ⅱ的α-螺旋含量升高,同时降低其β-转角和β...
The Influence of Transition Metal Ions on the Kinetics of Ascorbic Acid Oxidation by Methylene Blue in Strongly Acidic Media
The Influence of Transition Metal Ions the Kinetics of Ascorbic Acid Oxidation Methylene Blue
2010/4/22
The kinetics of the oxidation of L-ascorbic acid (H2 A) by methylene blue was investigated in strongly acidic media over the temperature range 22-40 oC. The kinetic studies were carried out as a funct...
Heavy Metal Contents of Lake Sapanca
Drinking water Natural lakes Motorway Metal pollution
2010/4/23
The heavy metal pollution of Lake Sapanca located in the Marmara region (Turkey), was investigated over time. The lake is the drinking water source of the city of Adapazarı and its environs. The ...
Determination of Fluoride and Some Metal Ion Levels in the Drinking Waters in Kayseri Province
Fluoride, metal ions drinking water preconcentration atomic absorption spectrometry
2010/6/27
Fluorine is one of the most common elements in the Earth's crust. Fluoride is recognized to be the most effective caries-preventive agent. The main sources of fluoride for people are generally food an...