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Abstract: Molecular dynamics computer simulations were used to study methanol molecules confined between the layers of 2:1 phyllosilicates. The model systems are based on natural Ca- and Na-rich montm...
Bentonite- and sepiolite-supported copper catalysts have been prepared either by adsorption of Cu(II) from aqueous solutions of copper nitrate at pH …4.5 or by adsorption ofa [Cu(NH3)4]2+ complex from...
The rate of sorption of methanol (MeOH), propan-2-ol (i-PrOH), and 2-methyl-propan-2-ol (t-BuOH) onto a Wyoming montmorillonite saturated with Al3+-, Cr3+-, or Fe3+-cations has been studied by isother...
The reactions of simple conjugated dienes over divalent and trivalent transition metal-exchanged montmorillonites yield, in the absence of nucleophiles, a variety of products. Some of these products a...
The acid-catalyzed reaction between methanol and isobutene to give methyl-t-butyl ether may be carried out using a cation-exchanged smectite as the catalyst. In 1,4-dioxan solvent at 60∑C smectites ex...

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