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The widely used two-product secondary organic aerosol (SOA) formation model has been extended in this study to consider the volatility changes of secondary organic gases (SOG) arising from the aging p...
Isoprene is the most abundant non-methane biogenic volatile organic compound (BVOC), but the processes governing secondary organic aerosol (SOA) formation from isoprene oxidation are only beginning to...
A new model for the formation of secondary organic aerosol (SOA) from isoprene was developed. This model uses surrogate molecular species (hydroxy-hydroperoxides, tetrols, methylglyceric acid, organic...
Because of the climate and air quality effects of organic aerosol, it is important to quantify the influence of anthropogenic emissions on the aerosol burden, both globally and regionally, and both in...
Diesel particulate matter (DPM) is a significant source of aerosol in urban areas and has been linked to adverse health effects. Although newer European directives have introduced increasingly stringe...
This paper provides an overview of SOA formation through aqueous chemistry, including atmospheric evidence for this process and a review of radical and non-radical chemistry, using glyoxal as a model ...
A large number of calculations of the absorptive partitioning of organic compounds have been made using a number of methods to predict the component vapour pressures, p0, and activity coefficients, γi...
In the present study, we have characterized the structure of a higher-molecular weight (MW) 358 α- and β-pinene dimeric secondary organic aerosol (SOA) product that received ample attention in previou...
Many recent models underpredict secondary organic aerosol (SOA) particulate matter (PM) concentrations in polluted regions, indicating serious deficiencies in the models' chemical mechanisms and/or mi...
Aldehydes are an important class of products from atmospheric oxidation of hydrocarbons. Isoprene (2-methyl-1,3-butadiene), the most abundantly emitted atmospheric non-methane hydrocarbon, produces a ...
We applied and compared seven vapor pressure estimation methods to the condensable compounds generated in the oxidation of α-pinene, as described by the state-of-the-art mechanism of the BOREAM model ...
The heterogeneous oxidation of laboratory Secondary Organic Aerosol (SOA) particles by OH radicals was investigated. SOA particles, produced by reaction of α-pinene and O3, were exposed to OH radicals...
Recent work has shown that aqueous-phase reactions of phenolic compounds – phenol (C6H6O), guaiacol (C7H8O2), and syringol (C8H10O3) – can form secondary organic aerosol (SOA) at high yields. Here we ...
The chemical and physical differences of secondary organic aerosol (SOA) formed at select isothermal temperatures (278 K, 300 K, and 313 K) are explored with respect to density, particle volatility, p...
Aqueous-phase oligomer formation from methylglyoxal, a major atmospheric photooxidation product, has been investigated in a simulated cloud matrix under dark conditions. The aim of this study was to e...

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