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2017年法拉第讨论：超分子和固态化学中的卤素键合（Halogen Bonding in Supramolecular and Solid State Chemistry-Faraday Discussion）
2017年 法拉第讨论 超分子和固态化学中的卤素键合
2017/1/20
Halogen bonding is a topic which continues to gain increased international attention across the chemical, biochemical, and materials sciences - this non-covalent interaction receiving a formal IUPAC d...
Modelling multi-phase halogen chemistry in the coastal marine boundary layer: investigation of the relative importance of local chemistry vs. long-range transport
multi-phase halogen chemistry the coastal marine boundary layer local chemistry long-range transport
2011/2/25
Measurements of significant concentrations of IO, I2 and BrO in a semi-polluted coast environment at Roscoff, in North-West France, have been made as part of the Reactive Halogens in the Marine Bounda...
Ozone variability and halogen oxidation within the Arctic and sub-Arctic springtime boundary layer
Ozone variability halogen oxidation the Arctic and sub-Arctic springtime boundary layer
2010/11/3
The influence of halogen oxidation on the variabilities of ozone (O3) and volatile organic compounds (VOCs) within the Arctic and sub-Arctic atmospheric boundary layer was investigated using field mea...
Coupling of HOx, NOx and halogen chemistry in the antarctic boundary layer
HOx, NOx and halogen chemistry the antarctic boundary layer
2010/11/3
A modelling study of radical chemistry in the coastal Antarctic boundary layer, based upon observations performed in the course of the CHABLIS (Chemistry of the Antarctic Boundary Layer and the Interf...
Comparative kinetic studies on the alkaline hydrolysis of halogen substituted isocoumarins
Hydrolysis isocoumarin kinetics
2010/10/18
Kinetics of the hydrolysis of 3-(2'-chloro-6'-fluorobenzyl) isocoumarin (1), 3-(4'-fluorophenyl)isocoumarin (3), 3-(2'- fluorophenyl)isocoumarin (5), 3-(2'-chlorophenyl)isocoumarin (7), and 3-(4'-chlo...
Measurement and modelling of tropospheric reactive halogen species over the tropical Atlantic Ocean
tropospheric reactive halogen species the tropical Atlantic Ocean
2010/8/13
Although tropospheric reactive halogen chemistry is well studied in coastal and polar environments, the presence of halogens over the open ocean environment has not been widely reported. The impacts o...
Synthesis, characterization, and application of nanoporous materials based on silicon- or halogen-containing spiroketal and spirothioketal polymers
Tetra(trimethylsilyl)-9,10-anthraquinone spiroketal polymers
2010/10/14
Organic microporous materials based on silicon-containing spiroketal and spirothioketal polymers were synthesized via a 1,3-dioxol-forming polymerization reaction between 1,1a,4,4a,5,5a,8, 8a-octahydr...
Modelling multi-phase halogen chemistry in the remote marine boundary layer: investigation of the influence of aerosol size resolution on predicted gas- and condensed-phase chemistry
Modelling multi-phase halogen chemistry remote marine boundary layer aerosol size resolution
2009/7/22
A coupled box model of photochemistry and aerosol microphysics which explicitly accounts for size-dependent chemical properties of the condensed-phase has been developed to simulate the multi-phase ch...
Release of reactive bromine and iodine from diatoms and its possible role in halogen transfer in polar and tropical oceans
Release of reactive bromine iodine from diatoms possible role halogen transfer in polar tropical oceans
2014/4/18
An in situ incubation assay measuring the bromination and iodination of phenol red was developed to detect the release of reactive bromine and iodine (primarily hypobromous acid [HOBr] and hypoiodous ...
Release of reactive bromine and iodine from diatoms and its possible role in halogen transfer in polar and tropical oceans
Release of reactive bromine diatoms halogen transfer
2014/4/18
An in situ incubation assay measuring the bromination and iodination of phenol red was developed to detect
the release of reactive bromine and iodine (primarily hypobromous acid [HOBr] and hypoiodous...
Halogen Occultation Experiment (HALOE) and balloon-borne in situ measurements of methane in stratosphere and their relation to the quasi-biennial oscillation（QBO）
Halogen Occultation Experiment HALOE quasi-biennial oscillation QBO
2009/3/11
Measurements of methane have been made from various observational platforms in the atmosphere. In this article, we have compared four high precision balloon-borne measurements from Hyderabad (17.5°N),...
A one dimensional model study of the mechanism of halogen liberation and vertical transport in the polar troposphere
halogen liberation vertical transport polar troposphere
2009/3/10
Sudden depletions of tropospheric ozone during spring were reported from the Arctic and also from Antarctic coastal sites. Field studies showed that those depletion events are caused by reactive halog...
A box model study on photochemical interactions between VOCs and reactive halogen species in the marine boundary layer
photochemical interactions VOCs reactive halogen species marine boundary layer
2009/3/6
A new chemical scheme is developed for the multiphase photochemical box model SEAMAC (size-SEgregated Aerosol model for Marine Air Chemistry) to investigate photochemical interactions between volatile...
Halogen cycling and aerosol pH in the Hawaiian marine boundary layer
Halogen cycling aerosol pH Hawaiian marine boundary layer
2009/2/20
Halogen species (HCl* (primarily HCl), Cl* (including Cl2 and HOCl), BrO, total gaseous inorganic Br and size-resolved particulate Cl- and Br -) and related chemical and physical parameters were measu...
Reactive and organic halogen species in three different European coastal environments
organic halogen species European coastal environments
2009/2/19
We present results of three field campaigns using active longpath DOAS (Differential Optical Absorption Spectroscopy) for the study of reactive halogen species (RHS) BrO, IO, OIO and I2. Two recent fi...